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Convergent synthesis of the tetrasaccharide repeating unit of the O-antigen of Shigella boydii type 9

By Abhishek Santra and Anup Kumar Misra

Abstract

A convenient synthesis of the tetrasaccharide repeating unit of the O-antigen of Shigella boydii type 9 has been achieved in excellent yield using a [2 + 2] block glycosylation strategy. TEMPO-mediated selective oxidation of the primary alcohol of the tetrasaccharide derivative 8 to the carboxylic group followed by deprotection of the functional groups furnished target tetrasaccharide 1 as its 4-methoxyphenyl glycoside in high yield

Topics: Full Research Paper
Publisher: Beilstein-Institut
OAI identifier: oai:pubmedcentral.nih.gov:3182426
Provided by: PubMed Central
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