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{4,4′-Dichloro-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methanyl­ylidene)]diphenolato-κ4 O,N,N′,O′}nickel(II)

By Hadi Kargar, Reza Kia, Elham Pahlavani and Muhammad Nawaz Tahir

Abstract

In the title compound, [Ni(C19H18Cl2N2O2)], the NiII atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the coordination rings is 9.15 (12)° while the dihedral angle between the mean planes of the two aromatic rings is 3.48 (16)°. In the crystal, pairs of inter­molecular C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by π–π inter­actions [centroid–centroid distance = 3.883 (2) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3151962
Provided by: PubMed Central

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Citations

  1. (2009). Acta Cryst. D65, 148–155. metal-organic compounds Acta Cryst.