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(2-Acetyl­phenolato)(2-{1-[2-(morpholin-4-yl)ethyl­imino]­eth­yl}phenolato)(thio­cyanato-κN)­cobalt(III)

By Chen-Yi Wang

Abstract

The title mononuclear cobalt(III) complex, [Co(C14H19N2O2)(C8H7O2)(NCS)], was obtained by the reaction of 2-acetyl­phenol, 2-(morpholin-4-yl)ethyl­amine, ammonium thio­cyan­ate and cobalt nitrate in methanol. The CoIII atom is coordinated by one phenolate O, one imine N, and one amine N atom of the tridentate Schiff base ligand, two O atoms of the 2-acetyl­phenolate anion and one thio­cyanate N atom. This results in a fairly regular fac-CoN3O3 octa­hedral coordination geometry for the metal ion. The dihedral angle between the two benzene rings is 88.3 (3)°

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3151850
Provided by: PubMed Central

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