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Aqua{2-(morpholin-4-yl)-N-[1-(2-pyri­dyl)ethyl­idene]ethanamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)manganese(II)

By Nura Suleiman Gwaram, Hamid Khaledi and Hapipah Mohd Ali


In the title compound, [Mn(NCS)2(C13H19N3O)(H2O)], the Schiff base acts as an N,N′,N"-tridentate ligand, forming two five-membered chelating rings with the MnII atom. The distorted octa­hedral geometry around the metal atom is completed by two cis-positioned N-bound thio­cyanate ligands and one water mol­ecule. In the crystal, adjacent mol­ecules are linked through O—H⋯O, O—H⋯S and C—H⋯S hydrogen bonds into a three-dimensional supra-mol­ecular structure. An intra­molecular C—H⋯O hydrogen bond also occurs

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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  1. (2010). metal-organic compounds m928 Suleiman Gwaram et al. doi:10.1107/S1600536811022124 Acta Cryst.