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Bis(N,N,N-trimethyl­ethanaminium) bis­(1,4-tetra­selenido-κ2 Se 1,Se 4)cadmate

By Jaemyeong Kim and Kang-Woo Kim

Abstract

The title compound, (EtMe3N)2[Cd(Se4)2], which has been prepared by reaction of CdI2, K2Se4 and EtMe3NI in dimethyl­formamide, is the first example of a [Cd(Se4)2]2− anion stabilized by alkyl­ammonium counter-ions. The Cd atom in the complex [Cd(Se4)2]2− anion is tetra­hedrally coordinated by two chelating tetra­selenide ligands, and both CdSe4 rings exhibit an envelope conformation

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3100066
Provided by: PubMed Central

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Citations

  1. (2008). Acta Cryst. A64, 112–122. metal-organic compounds m394 Kim and Kim doi:10.1107/S1600536811007227 Acta Cryst.
  2. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq Cd1