Article thumbnail

Poly[(μ-2-hy­droxy-3,5-dinitro­benzoato)rubidium]

By Yan Meng

Abstract

The asymmetric unit of the title compound, [Rb(C7H3N2O7)]n, comprises an Rb+ cation and a 3,5-dinitro­salicylate ligand. The Rb+ cation is 10-coordinated by O atoms from eight 3,5-dinitro­salicylate anions and is linked by three μ2-O atoms, forming a zigzag chain along the b-axis direction, which is further linked by the phenyl groups, giving the three-dimensional framework. The crystal structure involves intra-anionic O—H⋯O hydrogen bonds and strong π–π stacking inter­actions [centroid-centroid distance = 3.6755 (7) Å]

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3100035
Provided by: PubMed Central

To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.

Suggested articles

Citations

  1. (2007). Acta Cryst. E63, m399–m401. metal-organic compounds m454 Yan Meng doi:10.1107/S1600536811008476 Acta Cryst.
  2. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq Rb1