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4-Bromo-N-phenyl­aniline

By Emily J. Hefter and Joseph M. Tanski

Abstract

In the title compound, C12H10BrN, the dihedral angle between the benzene rings is 52.5 (1)°, whereas the pitch angles, or the angles between the mean plane of each aryl group ‘propeller blade’ and the plane defined by the aryl bridging C—N—C angle, are 19.6 (2) and 36.2 (3)°. While the N—H group is not involved in hydrogen-bonding inter­actions, the structure exhibits a network of inter­molecular C—H⋯π and N—H⋯π inter­actions

Topics: Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3099920
Provided by: PubMed Central

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Citations

  1. (2007). A view of the N—H···π intermolecular interaction with displacement ellipsoids shown at the 50% probability level [Symmetry codes: (i) x - 1/2, y + 3/2, -z]. 4-Bromo-N-phenylaniline Crystal data
  2. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq Br1
  3. (2002). Tanski Comment Diphenylamines have uses in chemical synthesis and materials chemistry, and they have been investigated for their biological activity (Krzymiński et al.,
  4. (2009). The structure reveals that there is no intermolecular hydrogen bonding, however, a network of intermolecular C—H···π and N—H···π bonds exists (Table 1), as in the isomorphous structure of 4-methoxy-N-phenylaniline (Krzymiński et al.,