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3,5-Diamino-4H-1,2,4-triazol-1-ium (6-carb­oxy­pyridine-2-carboxyl­ato)(pyridine-2,6-dicarboxyl­ato)cuprate(II) trihydrate

By S. Yousuf, A. S. Johnson, S. A. Kazmi, O. E. Offiong and Hoong-Kun Fun

Abstract

In the complex anion of the title compound, (C2H6N5)[Cu(C7H4NO4)(C7H3NO4)]·3H2O, the CuII atom is coordinated by tridentate 6-carb­oxy­pyridine-2-carboxyl­ate and pyridine-2,6-dicarboxyl­ate ligands and is surrounded by four O atoms in the equatorial plane and two N atoms in axial positions in a distorted octa­hedral geometry. In the crystal, the components are linked into a three dimensional network by O—H⋯O, N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds and a π–π inter­action with a centroid–centroid distance of 3.6080 (8) Å

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3099907
Provided by: PubMed Central

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Citations

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