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Tetraaqua­tetrakis­{μ2-[1-(carb­oxylato­meth­yl)cyclo­hex­yl]methanaminium}bis(μ3-hydroxido)bis(nitrato-κ2 O,O′)tetrazinc(II)

By Elise J. C. de Vries, Caryn Gamble and Ahmed Shaikjee

Abstract

As the title gabapentin complex, [Zn4(OH)2(NO3)2(C9H17NO2)4(H2O)4](NO3)4 is located about a centre of inversion, the asymmetric unit contains two disordered nitrate ions and half a complex mol­ecule. The two zinc ions have different coordination environments: one is slightly distorted octa­hedral and the other is trigonal–pyramidal. The conformation of the gabapentin mol­ecule is defined by the formation of two intra­molecular O—H⋯O hydrogen bonds. Furthermore, the ammonium H atoms are involved in numerous hydrogen bonds with the disordered nitrate anions

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3089351
Provided by: PubMed Central

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Citations

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  2. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq Occ.
  3. (2005). Packing diagram of complex (I) viewed down the b axis. Hydrogen atoms omitted for clarity. Tetraaquatetrakis{µ2-[1- (carboxylatomethyl)cyclohexyl]methanaminium}bis(µ3- hydroxido)bis(nitratoκ2O,O')tetrazinc(II) Crystal data