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tert-Butyl N-{(1S)-1-[(2,4-dihy­droxy­benzyl­idene)hydrazinecarbon­yl]-2-hy­droxy­eth­yl}carbamate ethanol monosolvate

By Alessandra C. Pinheiro, Marcus V. N. de Souza, Edward R. T. Tiekink, Solange M. S. V. Wardell and James L. Wardell

Abstract

The mol­ecule of the title ethanol solvate, C15H21N3O6·C2H6O, adopts a curved shape; the conformation about the imine bond [N=N = 1.287 (3) Å] is E. The amide residues occupy positions almost orthogonal to each other [dihedral angle = 85.7 (2)°]. In the crystal, a network of O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds leads to the formation of supra­molecular arrays in the ab plane with the ethanol mol­ecules lying to the periphery on either side. Disorder in the solvent ethanol mol­ecule was evident with two positions being resolved for the C atoms [site occupancy of the major component = 0.612 (10)]

Topics: Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:3052090
Provided by: PubMed Central

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