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{2-Morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ3 N,N′,N′′}bis­(thio­cyanato-κN)zinc(II)

By Nura Suleiman Gwaram, Nurul Azimah Ikmal Hisham, Hamid Khaledi and Hapipah Mohd Ali


The asymmetric unit of the title compound, [Zn(NCS)2(C13H19N3O)], contains two crystallographically independent mol­ecules. In each mol­ecule, the ZnII ion is five-coordinated by the N,N′,N"-tridentate Schiff base and the N atoms of two thio­cyanate ligands in a distorted square-pyramidal geometry. The two mol­ecules differ mainly in the deviations from the ideal geometry, with τ values of 0.14 and 0.33. In the crystal, inter­molecular C—H⋯S hydrogen bonds are observed. An intra­molecular C—H⋯N hydrogen bond occurs in one of the independent mol­ecules

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
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Provided by: PubMed Central

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