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Tetra­kis(μ-phenoxy­acetato-κ2 O:O′)bis­[(1,10-phenanthroline-κ2 N,N′)manganese(II)] methanol hemisolvate

By Dong-Hui Wu, Jian Shi, Yu-Jun Shi and Guo-Qing Jiang

Abstract

The title complex, [Mn2(C8H7O3)4(C12H8N2)2]·0.5CH3OH, is a carboxyl­ate-bridged dinuclear MnII complex with four phenoxy­acetate ions and two 1,10-phenanthroline mol­ecules as ligands. Each of the four phenoxy­acetate anions bridges the pair of Mn atoms. The asymmetric unit is completed by a half-occupancy methanol solvent mol­ecule. Face-to-face π–π stacking inter­actions between the aromatic rings of 1,10-phenanthroline molecules belonging to adjacent Mn2 complexes, with an inter­planar separation of circa 3.4 Å, and weak C—H⋯O hydrogen bonds connect the dinuclear units into a three-dimensional supra­molecular framework

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:2915099
Provided by: PubMed Central

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Citations

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  3. The π···π interactions and C—H···O hydrogen interactions in (I) are shown (dashed lines). Cg1 is the centroid of the interacting aromatic ring of 1,10-phenanthroline molecule in the asymmetric unit.

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