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Bis(acetyl­acetonato)oxido(triphenyl­phosphine oxide)vanadium(IV)

By Hui Chen, Youtao Si, Changneng Chen and Qiutian Liu

Abstract

In the structure of the title compound, [V(C5H7O2)2O(C18H15OP)], the V atom adopts a slightly distorted octa­hedral geometry with its coordination completed by four O atoms of two acetyl­acetonate (acac) ligands, one oxo group and one O atom of the triphenyl­phosphine oxide (OPPh3) ligand

Topics: Metal-Organic Papers
Publisher: International Union of Crystallography
OAI identifier: oai:pubmedcentral.nih.gov:2915097
Provided by: PubMed Central

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Citations

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  3. Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) x y z Uiso*/Ueq
  4. (1992). The presence of OPPh3 ligand in the compound was unexpected since the original reactant was PPh3. It has been shown in earlier studies that some metal oxo-complexes might react with PPh3 to give rise to OPPh3 due to their catalytic and redox properties