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Synthesis and Characterization of Some New Tetraaldehyde and Tetraketone Derivatives and X-ray Structure of 1,1′-(4,4′-(2-(1,3-bis(4-Acetylphenoxy)propan-2-ylidene)propane-1,3-di-yl)bis(oxy)bis(4,1-phenylene))diethanone

By Mustafa Er, Reşat Ustabaş, Ufuk Çoruh, Kemal Sancak and Ezequiel Vázquez-López

Abstract

Tetraketone and tetraaldehyde derivatives 2a–d were synthesized via the reaction of ethene-1,1,2,2,-tetra-yl-tetramethylene tetrabromide (1) with hydroxyketone and aldehyde derivatives. The molecular structures were identifed by IR, 1H-NMR, 13C-NMR and MS analysis. The crystal structure of the title compound 2a, C38H36O8, is reported. Its crystal data are: monoclinic, space group P 2(1)/n with cell dimensions of a=9.0395(12) Å, b=12.6114(17) Å, c=13.8166(18) Å, β=95.875(3), V=1566.8(4) Å3, F.W.=620.67, ρcalc=1.316 gcm3 for Z=2, μ=0.092 mm−

Topics: Article
Publisher: Molecular Diversity Preservation International (MDPI)
OAI identifier: oai:pubmedcentral.nih.gov:2658780
Provided by: PubMed Central
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