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Catalytic hydrodehalogenation of halon 1211 (CBrClF2) over carbon-supported palladium catalysts

By H. Yu, E.M. Kennedy, M. Azhar Uddin and B.Z. Dlugogorski

Abstract

The hydrodehalogenation of halon 1211 over Pd/C catalysts was studied over a relatively narrow temperature range, from 453 to 573 K. The main products of the reaction are CH2F2 and CHBrF2 with CHClF2 formed as a minor product. Pd/C catalysts show high initial activities but undergo gradual deactivation before reaching a steady-state activity level. Experimental results suggest that CHBrF2 and CHClF2 are formed via the secondary reaction of CF2 with HBr and HCl

Publisher: 'Elsevier BV'
Year: 2003
DOI identifier: 10.1016/s0926-3373(03)00074-2
OAI identifier: oai:researchrepository.murdoch.edu.au:27373
Provided by: Research Repository
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