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Synthesis of fluorinated allenes via palladium-catalyzed monofluoromethylation using FBSM

By Masamichi Ogasawara, Hidetoshi Murakami, Tatsuya Furukawa, Tamotsu Takahashi, Norio Shibata, ノリオ シバタ and 哲男 柴田

Abstract

Palladium-catalyzed monofluoromethylation of substituted 2-bromo-1,3-dienes using fluorobis(phenylsulfonyl)methane (FBSM) as a pronucleophile gave previously unknown monofluoromethylated allenes in high yields, which are the isosteres of biologically attractive allenic alcohols

Publisher: Royal Society of Chemistry
Year: 2009
DOI identifier: 10.1039/b912531k
OAI identifier: oai:repo.lib.nitech.ac.jp:123456789/4826
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