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Inter- and intramolecular Diels-Alder/retro-Diels-Alder \ud \ud reactions of 4-silylated oxazoles\ud

By P.C. Ducept and S.P. Marsden

Abstract

4-Silylated oxazoles have been shown to undergo inter- and intramolecular Diels-Alder/retro-Diels-Alder reactions with electron-poor alkynes to generate polysubstituted furans. The ease of synthesis of the requisite oxazoles by the rhodium-catalysed condensation of nitriles with silylated diazoacetate greatly increases the scope of this reaction

Year: 2002
OAI identifier: oai:eprints.whiterose.ac.uk:925

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