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Zinc Porphyrin−Re(I) Bipyridyl−Fullerene Triad: Synthesis, Characterization, and Kinetics of the Stepwise Electron-Transfer Processes Initiated by Visible Excitation

By P Cavigli, T Da Ros, A Kahnt, M Gamberoni, M T Indelli and E Lengo


A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in\ud remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation

Year: 2015
DOI identifier: 10.1021/ic502430e
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