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On the A1Π-X1Σ+ transition in BH: Λ-doubling and vibrational structure Ab initio calculations

By R. Cimiraglia and M. Persico


Ab initio electronic calculations were carried out on the ground X1Σ+ and the A1Π states. Bound and dissociative vibrational states are numerically computed to obtain the transition dipole moments of the discrete and continuum spectra. An example of theoretical evaluation of the Λ-doubling constant for the 1Π state is given to examine the feasibility of such calculations

Year: 1981
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