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4-[(4-Methylphenyl)sulfonyl]-1-(triphenylphosphoranylidene)-2-butanone as a convenient precursor for a new formal synthesis of KDO

By BARCO A., BASSETTI L., BENETTI S., BERTOLASI V., DE RISI C., MARCHETTI P. and POLLINI G.P.

Abstract

The application of 4-[(4-methylphenyl)sulfonyl]-1-(triphenylphosphoranylidene)-2-butanone, a readily available four-carbon building block, to the synthesis of 3-deoxy-D-manno-2-octulosonic acid (KDO) is described

Topics: 3-deoxy-D-manno-2-octulosonic acid, carbohydrates, diastereoselection, keto sulfones.
Year: 2002
DOI identifier: 10.1016/S0040-4020(02)00998-5
OAI identifier: oai:iris.unife.it:11392/1201521
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