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Enantioselective synthesis of (-)-meroquinene through tandem Michael reaction methodology

By BARCO A., BENETTI S., C. DE RISI, POLLINI G.P., ROMAGNOLI R., SPALLUTO G. and ZANIRATO V.

Abstract

An enantioselective approach to the synthesis of non natural (-)-meroquinene based on sequential inter- and intramolecular Michael reaction between (L)-menthyl N-benzyl-5-amino-2E-pentenoate and 1-acetyloxy-4-methoxymethyloxy-2-nitrobutane, acting as surrogate of 2-nitro-1,3-butadiene, is described

Publisher: Elsevier Science Limited:Oxford Fulfillment Center, PO Box 800, Kidlington Oxford OX5 1DX United Kingdom:011 44 1865 843000, 011 44 1865 843699, EMAIL: asianfo@elsevier.com, tcb@elsevier.co.UK, INTERNET: http://www.elsevier.com, http://www.elsevier.com/locate/shpsa/, Fax: 011 44 1865 843010
Year: 1994
DOI identifier: 10.1016/S0040-4020(01)86974-X
OAI identifier: oai:iris.unife.it:11392/461255
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