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Stereospecific nitromethane coniugate addition to 4-oxygenated-2-substituted cyclopent-2-enones: A simple approach to prostaglandins.

By P . G . BARALDI, A . BARCO, S. BENETTI, G . P . POLLINI, D . SIMONI and V . ZANIRATO.

Abstract

The compatibility of nitromethane conjugate addition to 2-cyclopentenones bearing a 4-oxygenated funtion has been illustrated trough a short and proctical sunthesis of Corey aldehyde. A new synthesis of PGF2a featuring the introduction of the omega-chain via [3+2] cycloaddition has been described

Year: 1987
OAI identifier: oai:iris.unife.it:11392/460284
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