Article thumbnail
Location of Repository

1,3-Bis(1,2,4-triazolyl)adamantine-based Coordination Polymers

By N. Xhaferaj, A. Tabacaru, C. Pettinari, F. Marchetti, S. Galli, N. Masciocchi and K. V. Domasevitch

Abstract

The hybrid organic-inorganic materials known as coordination polymers are continuously gaining ground of scientific research, especially due to the interesting and promising functionalities they possess, e.g. magnetic, optical, electrical, redox, and luminescence properties, as well as, when permanent porosity is present, gas adsorption or separation, catalytic activity, and drug delivery. The reaction of the flexible ligand 1,3-bis(1,2,4-triazolyl)adamante (tr2ad, Scheme 1) with chlorides of different late transition metals, either following conventional routes or under solvothermal conditions, afforded the coordination polymers having the general stoechiometric formula of the type M(tr2ad)Cl2 (M = Zn,1; Cu, 2; Cd, 3; Ni, 4; Co, 5). Preliminary ab initio X-ray powder diffraction analyses revealed that 1 developes into a 1-D polymeric chain, while 2 features a 2-D polymeric structure. Thermal-gravimetric analyses (TGA) showed relevant thermal robustness of all these materials, peaking up to the onset of decomposition set at 350 °C

Publisher: La nuova stampa- Camerino
Year: 2014
OAI identifier: oai:pubblicazioni.unicam.it:11581/322986
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://hdl.handle.net/11581/32... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.