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Complete Series of Chiral Paramagnetic Molecular Conductors Based on Tetramethyl-bis(ethylenedithio)-tetrathiafulvalene (TM-BEDT-TTF) and Chloranilate-Bridged Heterobimetallic Honeycomb Layers

By M. Atzori, F. Pop, P. Auban-Senzier, R. Clérac, E. Canadell, M.Laura Mercuri and N. Avarvari


This article reports on the crystal structure and the physical properties of a complete series of isostructural chiral molecular conductors obtained combining the TM-BEDT-TTF organic donor as (S,S,S,S) and (R,R,R,R) enantiopure forms, or racemic mixture (rac), with heterobimetallic anionic layers obtained “in situ” by the self-assembling of tris(chloranilato)ferrate(III) metal complexes and potassium cations

Publisher: 'American Chemical Society (ACS)'
Year: 2015
DOI identifier: 10.1021/acs.inorgchem.5b00261
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Provided by: Okina

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