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The isotope hydrology of Quaternary climate change

By W.G. Darling


Understanding the links between climate change and human migration and culture is an important theme in Quaternary archaeology. While oxygen and hydrogen stable isotopes in high-latitude ice cores provide the ultimate detailed record of palaeoclimate extending back to the Middle Pleistocene, groundwater can act as a climate archive for areas at lower latitudes, permitting a degree of calibration for proxy records such as lake sediments, bones, and organic matter. Not only can oxygen and hydrogen stable isotopes be measured on waters, but the temperature of recharge can be calculated from the amount of the atmospheric noble gases neon, argon, krypton, and xenon in solution, while residence time can be estimated from the decay of the radioisotopes carbon-14, chlorine-36, and krypton-81 over timescales comparable to the ice core record. The Pleistocene–Holocene transition is well characterised in aquifers worldwide, and it is apparent that isotope–temperature relationships of the present day are not necessarily transferable to past climatic regimes, with important implications for the interpretation of proxy isotope data. Groundwaters dating back to one million years, i.e., to beyond the Middle Pleistocene, are only found in major aquifer basins and information is relatively sparse and of low resolution. Speleothem fluid inclusions offer a way of considerably increasing this resolution, but both speleothem formation and large-scale groundwater recharge requires humid conditions, which may be relatively infrequent for areas currently experiencing arid climates. Both types of record therefore require caution in their interpretation when considering a particular archaeological context.\ud \u

Publisher: Elsevier
Year: 2011
DOI identifier: 10.1016/j.jhevol.2010.05.006
OAI identifier: oai:nora.nerc.ac.uk:14208

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  2. (2003). A comparison of groundwater dating with 81Kr, 36Cl and 4He in four wells of the Great Artesian Basin, doi
  3. (2008). A new tool for palaeoclimate reconstruction: Noble gas temperatures from fluid inclusions in speleothems. doi
  4. (2009). A record of temperature and monsoon intensity over the past 40 kyr from groundwater in the North China Plain. doi
  5. (2010). Accurate analysis of noble gas concentrations in small water samples and its application to fluid inclusions in stalagmites.
  6. (2005). Assessing the applicability of isotopic analysis of pedogenic gypsum as a paleoclimate indicator: Jornada and Tularosa basins,
  7. (2003). Changing moisture sources over the last 330,000 years in Northern Oman from fluid-inclusion evidence in speleothems.
  8. (2006). Chlorine-36 dating of deep groundwater from northern Sahara.
  9. (1986). Chlorine-36 dating of very old groundwater, II. Milk River aquifer,
  10. (2009). Climate variability in the Upper Jordan Valley around 0.78 Ma, inferences from time-series stable isotopes of Viviparidae, supported by mollusc and plant palaeoecology.
  11. (2009). Climatic and environmental controls on speleothem oxygen-isotope values. doi
  12. (2000). Cool Glacial temperatures and changes in moisture source recorded in Oman groundwaters. doi
  13. (1995). Cooling of tropical Brazil (5°C) during the last glacial maximum.
  14. (1989). Dating of late Pleistocene interglacial and interstadial periods in the United Kingdom from speleothem growth frequency.
  15. (1974). Desert isotope hydrology: water sources of the Sinai Desert.
  16. (1986). Dissolved gas paleotemperatures and 18O variations derived from groundwater near Uitenhage,
  17. (2004). Eight glacial cycles from an Antarctic ice core.
  18. (1989). Environmental isotope study (14C, 13C, 18O, D, noble gases) on deep groundwater circulation systems in Hungary.
  19. (1997). Environmental Isotopes in Hydrogeology.
  20. (2000). ESR dating: is it still an „experimental‟ technique?
  21. (2000). Estimate of recharge from radiocarbon dating of groundwater and numerical flow and transport modeling. doi
  22. (1992). Estimating paleorecharge and paleoclimate from unsaturated zone profiles,
  23. (2001). Evolution of the Aveiro Cretaceous aquifer (NW Portugal) during the Late Pleistocene and preset day: evidence from chemical and isotopic data.
  24. (1985). Fossil Water under the Sinai-Negev Peninsula.
  25. (2001). From Africa to Eurasia – early dispersals.
  26. (2002). Further research at the Oldowan site of Aïn Hanech, north-eastern Algeria.
  27. (2002). Geochemical and stable isotopic evolution of the Guarani Aquifer System in the state of São Paulo,
  28. (2009). Geochemical evolution of groundwater in the Cambrian–Vendian aquifer system of the Baltic Basin.
  29. (1979). Glacial/interglacial temperature variations in Soreq cave speleothems as recorded by 'clumped isotope' thermometry.
  30. (2004). Groundwater as an archive of climatic and environmental change. The Pep-III Traverse. In: Battarbee,
  31. (2003). Groundwater evolution in the Continental Intercalaire aquifer of Southern Algeria and Tunisia: trace element and isotopic indicators.
  32. (1992). He as a semi-quantitative tool for groundwater dating in the range of 104 to 108 years. In:
  33. (2008). Helium-4 characteristics of groundwaters from Central Australia: Comparative chronology with chlorine-36 and carbon-14 dating techniques. doi
  34. (2007). High- and low-latitude forcing of Plio-Pleistocene East African climate and human evolution.
  35. (2005). Hominin responses to Pleistocene environmental change in Arabia and South Asia.
  36. (2000). Hydrochemistry and hydrodynamics of the Cadna-Owie – Hooray aquifer, Great Artesian Basin. Bureau of Rural Sciences,
  37. (2004). Hydrological factors in the interpretation of stable isotopic proxy data present and past: a European perspective.
  38. (1999). Interpretation of dissolved atmospheric noble gases in natural waters.
  39. (1997). Isotopic evidence for palaeowaters in the British Isles.
  40. (1993). Isotopic patterns in modern global precipitation. In:
  41. (1961). Isotopic variations in meteoric waters.
  42. (2008). Method for purification of krypton from environmental samples for analysis of radiokrypton isotopes. doi
  43. (1967). Modification of the isotopic composition of rainwater by processes which occur before groundwater recharge. In: Isotopes
  44. (2007). New isotopic evidence for the origin of groundwater from the Nubian Sandstone Aquifer in the Negev, doi
  45. (1997). Noble gas recharge temperatures and the excess air component. doi
  46. (2002). Noble gases in lakes and ground waters. doi
  47. (1990). Nubian aquifer system. In
  48. (2009). On the accuracy of noble gas recharge temperatures as a paleoclimate proxy.
  49. (1972). On the ancient waters of the Upper Nubian sandstone waters in Sinai and
  50. (2004). One million year old groundwater in the Sahara revealed by krypton-81 and chlorine-36.
  51. (2001). Oxygen isotope and palaeotemperature records from six Greenland ice-core stations:
  52. (1978). Paleoclimatic information from deuterium and oxygen-18 in carbon-14-dated north Saharian groundwaters. In: Isotope Hydrology, International Atomic Energy Agency,
  53. (1972). Paleotemperatures and other hydrological parameters deduced from gases dissolved in groundwaters, doi
  54. (1992). Paleotemperatures in the southwestern United States derived from noble gas measurements in groundwater.
  55. (2000). Pleistocene milestones on the Out-of-Africa Corridor at Gesher Benot Ya'akov,
  56. (1993). Principles and applications of the noble gas paleothermometer. In: Climate Change in Continental Isotopic Records.
  57. (1998). Rainfall-recharge relationships within a karstic terrain in the eastern Mediterranean semi-arid region, Israel: δ18O and δD characteristics.
  58. (1992). Relation between long-term trends of oxygen-18 isotope composition of precipitation and climate.
  59. (1987). Sources of recharge to the Basal Nubian Sandstone aquifer, Butana Region,
  60. (2009). Speleothems from the earliest Quaternary: snapshots of paleoclimate and landscape evolution at the northern rim of the Alps.
  61. (2006). Stable isotope microsampling of speleothems: a comparison of drill, micromill and laser ablation techniques.
  62. (1964). Stable isotopes in precipitation.
  63. (1999). The correlation between 18O/16O ratios of meteoric water and surface temperature: Its use in investigating terrestrial climate change over geological time. Earth Planet.
  64. (2008). The first hominin of Europe,
  65. The Great Artesian Basin,
  66. (2003). The isotope hydrology of Quaternary climate change
  67. (2004). The isotope hydrology of Quaternary climate change Feibel, C.S.,
  68. (1978). The isotope hydrology of Quaternary climate change Sofer, Z.,
  69. (1980). The isotopes of hydrogen and oxygen in precipitation.
  70. (2008). The noble gas geochemistry of natural CO2 gas reservoirs from the Colorado Plateau and Rocky Mountain provinces,
  71. (2001). The recovery and isotopic measurement of water from fluid inclusions in speleothems.
  72. (2007). U-ages in soils and groundwater evidencing wet periods 400–600 kyr ago in southeast Brazil.
  73. (2006). U–Pb geochronology of speleothems by MC-ICPMS. doi
  74. (1992). Uranium-series dating and the origin of modern man.
  75. (2006). Uranium-series dating applications in natural environmental science.
  76. (1996). Water resources.

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