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oaioai:eprints.whiterose.ac.uk:3751

Macropolyhedral boron-containing cluster chemistry. Cluster assembly about a molybdenum centre. Formation of the 19-vertex [(CO)(2)MoB16H15C2Ph2](-) anion

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    Abstract

    Fusion of nine-vertex [1-Ph-nido-1-CB8H11] with [Mo(CH3CN)3(CO)3] in the presence of tetramethylnaphthalenediamine gives the nineteen-vertex macropolyhedral metallaborane anion [(CO)2MoB16H15C2Ph]− with a molybdenum(VI) twelve-atom coordination sphere

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      This paper was published in White Rose Research Online.

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