Skip to main content
Article thumbnail
Location of Repository

Image states in metal clusters

By P Rinke, K Delaney, P Garcia-Gonzalez and R W Godby

Abstract

The existence of image states in small clusters is shown, using a quantum-mechanical many-body approach. We present image state energies and wave functions for spherical jellium clusters up to 186 atoms, calculated in the GW approximation, where G is the Green's function and W is the dynamically screened Coulomb interaction, which by construction contains the dynamic long-range correlation effects that give rise to image effects. In addition, we find that image states are also subject to quantum confinement. To extrapolate our investigations to clusters in the mesoscopic size range, we propose a semiclassical model potential, which we test against our full GW results

Year: 2004
OAI identifier: oai:eprints.whiterose.ac.uk:4020

Suggested articles


To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.