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Inhomogeneous phase transition upon hydrogenation of nanocluster Pd films

By M. Di Vece, J.J. Kelly and P. Lievens


A combination of electrochemical and optical techniques is used to study the interaction of hydrogen with palladium nanoclusters. Hydrogen pressure-composition isotherms reveal the reduced presence of the phase in palladium nanoclusters. Hydrogen extraction transients relate the reduced miscibility gap to a core-shell phase transformation in the palladium nanoclusters

Year: 2009
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