Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

Abstract

The telomerization of 1,3-butadiene with various alcohols has been investigated using a catalyst based on a Pd(acac)(2) precursor and a phosphine ligand, TOMPP (TOMPP = tris-(o-methoxyphenyl)phosphine). We were able to demonstrate the capability of the catalyst to telomerize 1,3-butadiene with various multifunctional nucleophiles having primary and secondary alcohol functions. High yields of telomer products (>98%) were obtained in very short reaction times

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Utrecht University Repository

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Last time updated on 14/06/2016

This paper was published in Utrecht University Repository.

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