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Base-free Pd/TOMPP-Catalyzed Telomerization of 1,3-Butadiene with Carbohydrates and sugar alcohols

By P.J.C. Hausoul, P.C.A. Bruijnincx, R.J.M. Klein Gebbink and B.M. Weckhuysen

Abstract

Sugar and alcohol - a superior combo: The telomerization activity of the Pd/TOMPP catalyst is screened using thirteen different biomass-derived carbohydrates and sugar alcohols. High substrate conversions are achieved by using low Pd loading and without the use of an added base. In terms of butadiene conversion, a clear structure-activity relationship is found, which is in line with the series: sugar alcohols>sucrose>aldohexoses>aldopentoses>ketohexose

Topics: International (English)
Year: 2009
OAI identifier: oai:dspace.library.uu.nl:1874/40928
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