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In-Plane Stacking Disorder in Polydisperse Hard Sphere Crystals

By J.M. Meijer, V.W.A. de Villeneuve and A.V. Petukhov

Abstract

We demonstrate that in random-stacking hard-sphere colloidal crystals the stacking disorder not only exists in the direction perpendicular to the close-packed layers, but also extends in the lateral direction. The existence of such in-plane stacking disorder is suggested by a recent observation of lateral broadening of the Bragg scattering rods in microradian X-ray diffraction and is further confirmed here by real-space confocal microscopy in two hard-sphere colloidal systems with different relative gravity effects. Due to the in-plane stacking disorder, the hexagonal planes consist of islands with different lateral A, B, and C positions with characteristic line defects in between them. The real-space layer-by-layer stacks of images also reveal the 3-D structure of the defects. The chance ξ to find another line-defect above a line-defect in the layer below turns out to be close to 1/2sindependent of relative gravityswhich can be explained by the two different stacking options above a defect. The stacking of a few sets of several line defects situated on top of each other turns out to be predominantly FCC-like

Year: 2007
OAI identifier: oai:dspace.library.uu.nl:1874/26654
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