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Biomimetic synthesis of neodihydrothebaine and bractazonine from thebaine

By C.A. Salemink, H.G. Theuns, G.F. La Vos and M.C. ten Noever de Brauw


Photochemical irradiation of the morphinan alkaloid thebaine 1 followed by reduction, affords the dibenz[d,f]azonine alkaloids neodihydrothebaine 2 and bractazonine 3, in a sequence paralleling the proposed biosynthesis of these alkaloids in Papaver bracteatum

Topics: Scheikunde
Year: 1984
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