Skip to main content
Article thumbnail
Location of Repository

121Sb Mössbauer studies on dialkylantimony(V) compounds of the types R2Sb(OMe)3, R2Sb(OAc)3 and R2Sb(O)OH

By J.G. Stevens, J.M. Trooster and H.A. Meinema


Mössbauer spectra of three series of dialkylantimony(V) compounds have been measured to study bonding and structural properties of these compounds. Trialkoxodialkyl and triacetatodialkylantimony(V) compounds have octahedral structure. The former are dimeric, containing bridging methoxo groups, the latter are monomeric, containing a bidentate acetato ligand, for which the bite angle is distorted from 90°. Dialkylstibinic acids, R2Sb(O)OH, have tetrahedral coordination around the antimony atom. The additive model for the Electric Field Gradient is used to interpret much of the quadrupole coupling data

Topics: Scheikunde
Year: 1980
OAI identifier:
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • (external link)
  • Suggested articles

    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.