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Increasing the Lipophilic Character of Tetraphenylborate Anions through Silyl Substituents

By G. van Koten, J. van den Broeke, M.H. Lutz, H. Kooijman, A.L. Spek and B.J. Deelman


Trimethylsilyl- and dimethyl(1H,1H,2H,2H-perfluorooctyl)silyl substituents have been introduced in the para position of tetraphenylborate anions, resulting in enhanced solubility of their complexes n-Bu4N[B(C6H4SiMe2R-4)4] (R = Me, CH2CH2C6F13) and [Rh(dppe)2][B(C6H4SiMe2R-4)4] (dppe = 1,2-bis(diphenylphosphino)ethane, R = Me, CH2CH2C6F13) in apolar organic solvents

Topics: Scheikunde
Year: 2001
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