Increasing the Lipophilic Character of Tetraphenylborate Anions through Silyl Substituents

Koten, G. van; Broeke, J. van den; Lutz, M.H.; Kooijman, H.; Spek, A.L.; Deelman, B.J.

oai:dspace.library.uu.nl:1874/6280

Increasing the Lipophilic Character of Tetraphenylborate Anions through Silyl Substituents

Authors: G. van Koten
J. van den Broeke
M.H. Lutz
H. Kooijman
A.L. Spek
B.J. Deelman
Publication date: 1 January 2001
Publisher

Abstract

Trimethylsilyl- and dimethyl(1H,1H,2H,2H-perfluorooctyl)silyl substituents have been introduced in the para position of tetraphenylborate anions, resulting in enhanced solubility of their complexes n-Bu4N[B(C6H4SiMe2R-4)4] (R = Me, CH2CH2C6F13) and [Rh(dppe)2][B(C6H4SiMe2R-4)4] (dppe = 1,2-bis(diphenylphosphino)ethane, R = Me, CH2CH2C6F13) in apolar organic solvents

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