Location of Repository

Application of N,S-Chelating chiral Zinc bis(Arenthiolate) Complexes as New Precursor Catalysts in the Enantioselective Addition of diethylzinc to Aldehydes

By G. van Koten, E. Rijnberg, J.T.B.H. Jastrzebski, M.D. Janssen and J. Boersma

Abstract

The addition of diethylzinc to aldehydes in the presence of a catalytic amount of enantiomerically pure N, S-chelated bis{2-[(R)-1-(dimethylamino)ethyl]phenylthiolato}zinc, afforded the corresponding secondary alcohols in nearly quantitative yields with optical purities of up to 99 % e.e. under mild reaction conditions

Topics: Scheikunde
Year: 1994
OAI identifier: oai:dspace.library.uu.nl:1874/6091
Download PDF:
Sorry, we are unable to provide the full text but you may find it at the following location(s):
  • http://dspace.library.uu.nl:80... (external link)
  • Suggested articles


    To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.