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The use of diazabicyclo[2.2.2]octane as a novel highly selective dechloroacetylation reagent

By J.F.G. Vliegenthart, D.J. Lefeber and J.P. Kamerling

Abstract

In a study directed toward the use of the chloroacetyl protecting group in carbohydrate synthesis, the sterically hindered tertiary amine diazabicyclo[2.2.2]octane (DABCO) was found to give complete and selective cleavage of the chloroacetyl group in the presence of other ester functions such as benzoyl and acetyl groups at primary and/or secondary positions

Topics: Scheikunde
Year: 2000
OAI identifier: oai:dspace.library.uu.nl:1874/5804
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