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Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl)

By Mokhtar Imit, Takakazu Yamamoto and Patigul Imin


Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated polymer, which can only be dissolved in strong acids such as formic acid) and allows mixing the protonated polymers with other chloroform soluble conjugated polymers for use in electronic devices. The protonating behavior of poly(pyridine-2,5-diyl) with two kinds of surfactants is different in some levels. Dodecybenzenesulfonic acid has higher protonating ability than camphorsulphonic acid

Topics: Chemistry & Chemical Engineering
Publisher: Zhejiang University Press
OAI identifier: oai:pubmedcentral.nih.gov:1389751
Provided by: PubMed Central
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