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An Automated Analyzer to Measure Surface-Atmosphere Exchange Fluxes of Water Soluble Inorganic Aerosol Compounds and Reactive Trace Gases

By Rick M. Thomas, Ivonne Trebs, René Otjes, Piet A. C. Jongejan, Harry ten Brink, Gavin Phillips, Michael Kortner, Franz X. Meixner and Eiko Nemitz

Abstract

Here, we present a new automated instrument for semicontinuous gradient measurements of water-soluble reactive trace gas species (NH3, HNO3, HONO, HCl, and SO2) and their related aerosol compounds (NH4+, NO3−, Cl−, SO42−). Gas and aerosol samples are collected simultaneously at two heights using rotating wet-annular denuders and steam-jet aerosol collectors, respectively. Online (real-time) analysis using ion chromatography (IC) for anions and flow injection analysis (FIA) for NH4+ and NH3 provide a half-hourly averaged gas and aerosol gradients within each hour. Through the use of syringe pumps, IC preconcentration columns, and high-quality purified water, the system achieves detection limits (3σ-definition) under field conditions of typically: 136/207, 135/114, 29/22, 119/92, and 189/159 ng m−3 for NH3/NH4+, HNO3/NO3−, HONO/NO2−, HCl/Cl− and SO2/SO42−, respectively. The instrument demonstrates very good linearity and accuracy for liquid and selected gas phase calibrations over typical ambient concentration ranges. As shown by examples from field experiments, the instrument provides sufficient precision (3−9%), even at low ambient concentrations, to resolve vertical gradients and calculate surface−atmosphere exchange fluxes under typical meteorological conditions of the atmospheric surface layer using the aerodynamic gradient technique

Topics: Meteorology and Climatology, Ecology and Environment, Atmospheric Sciences, Electronics, Engineering and Technology
Year: 2009
DOI identifier: 10.1021/es8019403
OAI identifier: oai:nora.nerc.ac.uk:6587
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