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Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine

By Margarita Paneque, Manuel L. Poveda, Florencia Vattier, Eleuterio Álvarez and Ernesto Carmona

Abstract

Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine behaves, respectively, as a mono- or a bi-dentate N-heterocyclic carbene.Peer Reviewe

Publisher: 'Royal Society of Chemistry (RSC)'
Year: 2015
DOI identifier: 10.1039/B909837B
OAI identifier: oai:digital.csic.es:10261/109779
Provided by: Digital.CSIC
Journal:

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