Levels and trends of the emerging contaminants HBCDs (hexabromocyclododecanes) and PFCs (perfluorinated compounds) in marine shellfish along French coasts


The levels and congener patterns of HBCDs (hexabromocyclododecanes) and PFCs (perfluorinated compounds) were determined in filter-feeding molluscs collected in 2008 and 2010 along the coasts of mainland France. alpha-HBCD and PFOS (perfluorooctane sulfonate) were detected in all samples, revealing widespread contamination of the coastal environment by these emerging contaminants. The spatial distribution of Sigma-HBCD concentrations showed higher median levels in samples from the Mediterranean Sea and English Channel respectively, i.e. 0.19 ng g(-1) wet weight (ww) and 0.08 ng g(-1) ww, related to high anthropogenic pressure from urban and industrial activities, while the median concentration was 0.05 ng g(-1) ww in samples from the Atlantic coast. Among PFCs, PFOS was the only compound detected in all samples and PFDA (perfluorodecanoic acid) was the second most frequently-detected compound. PFOS median concentrations were 0.18 ng g(-1) ww, 0.09 ng g(-1) ww and 0.04 ng g(-1) ww in samples from the English Channel, the Atlantic coast and the Mediterranean coast respectively. The highest PFOS concentration was found in the Loire estuary, possibly related to local industrial activities. The Mediterranean samples showed a different pattern, with predominant long-chain PFCAs (perfluorocarboxylic acids), suggesting the presence of alternative sources on the Mediterranean coast. The temporal trends studied in archived samples from the Seine estuary site showed a significant exponential increase in HBCD concentrations between 1981 and 2011, with a doubling time of 7 years, while PFOS levels underwent a significant linear decrease over time. These trends are coherent with current regulations on the use of these compounds. The results presented in this paper provide the first data on the contamination of the French coastal marine environment by the selected emerging compounds, and constitute a reference for the future monitoring of French coastal contamination by emerging contaminants

Similar works

Full text


ArchiMer - Institutional Archive of Ifremer

Full text is not available
oai:archimer.ifremer.fr:28765Last time updated on 5/9/2016

This paper was published in ArchiMer - Institutional Archive of Ifremer.

Having an issue?

Is data on this page outdated, violates copyrights or anything else? Report the problem now and we will take corresponding actions after reviewing your request.