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Anion complexation and electrochemical behaviour of ferrocene-appended amido-pyrrole clefts

By Guy Denuault, Philip A. Gale, Michael B. Hursthouse, Mark E. Light and Colin N. Warriner


Two amido-pyrrole cleft anion receptors bearing two ferrocene reporter groups have been synthesised and crystallographically characterised; the receptors contain either a non-conjugated or conjugated link between the anion-binding amido-pyrrole unit and the ferrocene reporter groups. <br/>The anion binding a?nities and electrochemical behaviour of the receptors in the absence and presence of anions have been studied by 1H NMR titration techniques and cyclic voltammetry using a Pt microdisc working electrode, respectively

Topics: QD
Year: 2002
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Provided by: e-Prints Soton
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