oaioai:repositorio.uam.es:10486/690789

Asymmetric trifluoromethylthiolation of azlactones under chiral phase transfer catalysis

Abstract

The first enantioselective method for the installation of the SCF3 group at the C-4 position of azlactones is described in the present communication under quinidinium phase transfer catalysis. The higher performance of substrates containing electron-rich 2-aryl groups at the azlactone was rationalized using DFT calculationsWe are grateful to the Spanish Government (RTI2018-095038-B-I00, CTQ, CTQ2016-76061-P), “Comunidad de Madrid” and European Structural Funds (S2018/NMT-4367

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oaioai:repositorio.uam.es:10486/690789Last time updated on 5/14/2020

This paper was published in Biblos-e Archivo.

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