Skip to main content
Article thumbnail
Location of Repository

Extension of the thermodynamics of small systems to open metastable states: An example

By Terrell L. Hill and Ralph V. Chamberlin


By using a simplified model of small open liquid-like clusters with surface effects, in the gas phase, it is shown how the statistical thermodynamics of small systems can be extended to include metastable supersaturated gaseous states not too far from the gas–liquid equilibrium transition point. To accomplish this, one has to distinguish between mathematical divergence and physical convergence of the open-system partition function

Topics: Physical Sciences
Publisher: The National Academy of Sciences
Year: 1998
OAI identifier:
Provided by: PubMed Central
Sorry, our data provider has not provided any external links therefore we are unable to provide a link to the full text.

Suggested articles

To submit an update or takedown request for this paper, please submit an Update/Correction/Removal Request.