Stereochemical course of the formation of the C(7)-formyl group from a chiral methyl group during the transformation of chlorophyllide a into chlorophyllide b
The biosynthesis of chlorophyll a and chlorophyll b from (2R,3R)- and (2S,3S)-5-amino[2,3-14C2,2,3-
2H2,2,3-3H2]levulinic acid in greening barley has established that chlorophyllide a oxidase catalyses the
transformation of the methyl group at C(7) of chlorophyllide a into the CHO group of chlorophyllide b with the
loss of HSi from the 7-(hydroxymethyl)chlorophyllide intermediate
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