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Synthesis of poly(vinyl acetate)-based nanogels via cobalt-mediated radical polymerization (CMRP)

By Mathilde Weiss-Maurin, Christine Jérôme, Daniel Taton and Christophe Detrembleur

Abstract

Cobalt-Mediated Radical Polymerization (CMRP) is one of the most efficient techniques to form sequenced copolymers between monomers of very different reactivities(e.g. vinyl acetate and acrylonitrile). CMRP is used here to synthesize nanogels of poly(vinyl acetate) using different concentrations of cross-linking agent (divinyl adipate). The aim is to determine the structure of the nanogels, in order to use them for the preparation of star-like and/or core-shell structures

Topics: radical polymerization, cobalt-mediated radical polymerization (CMRP), Physical, chemical, mathematical & earth Sciences :: Chemistry, Physique, chimie, mathématiques & sciences de la terre :: Chimie, Engineering, computing & technology :: Materials science & engineering, Ingénierie, informatique & technologie :: Science des matériaux & ingénierie
Year: 2013
OAI identifier: oai:orbi.ulg.ac.be:2268/201832
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