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Studies on the complexes of 3-(o-carboxyphenyl)-1-phenyltriazene 1-oxide : Part I-Zinc(II) complex and its reaction products with some neutral N-donors

By Sailesh C Saha and Subrata Maji

Abstract

573-576Zinc(II) forms the complex ZnL(H2O)2 with 3-(o-carboxyphenyl)-1-phenyltriazene 1-oxide (LH2).The complex has been characterised, along with its reaction products with some neutral N-donors (X); on the basis of elemental analysis and IR and 1H NMR studies. Thermal properties and isolable intermediates of thermolysis of the complexes have also been studied. In all the complexes the triazene 1-oxide behaves as a dibasic tetradentate ligand (O-, N-, O2) showing a marked tendency to form mixed ligand complexes

Publisher: NISCAIR-CSIR, India
Year: 1990
OAI identifier: oai:localhost:123456789/46383
Provided by: NOPR

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