Wagner-Meerwein Skeletal Rearrangement of 3-Spiroannulated 6,8a-Epoxy- and 6,8a;7,8-Diepoxyisoquinolines (3-Aza-11-oxatricyclo[6.2.1.0 1,6]undec-9-enes). Isolation and Identification of 5-Aza-2-oxatricyclo[6.2.1.03,9]undec-3-enes
Abstract
The reactions of 3-acetyl-3-aza-11-oxatricyclo[6.2.1.0 1,6]undec-9-ene and its 9,10-epoxy derivative with bromine and Ac2O/BF3·OEt2 under different conditions were studied. Unusual products of Wagner-Meerwein rearrangement bearing the olefin fragment (5-aza-2-oxatricyclo[6.2.1.0 3,9]-undecen-3-enes) were isolated and characterized by X-ray analysis- Article
- Bromine
- Derivatives
- Olefins
- Reaction kinetics
- X ray analysis
- Olefin fragments
- Aromatic compounds
- 5 aza 2 oxatricyclo[6.2.1.0 3,9]undec 3 ene
- 6,8a epoxyisoquinoline (3 aza 11 oxatricyclo[6.2.1.0 1,6]undec 9 ene)
- 6,8a:7,8 diepoxyisoquinoline (3 aza 11 oxatricyclo[6.2.1.0 1,6]undec 9 ene)
- bromine
- decane
- epoxide
- ether
- isoquinoline derivative
- unclassified drug
- article
- carbon nuclear magnetic resonance
- chemical analysis
- chemical structure
- proton nuclear magnetic resonance
- reaction analysis
- structure analysis
- Wagner Meerwein rearrangement
- X ray analysis
Similar works
Full text
Last time updated on 04/04/2020
This paper was published in National Open Repository Aggregator (NORA).
Having an issue?
Is data on this page outdated, violates copyrights or anything else? Report the problem now and we will take corresponding actions after reviewing your request.