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Variable coordination chemistry of the phospha(III)guanidinate anion; application as a metal-functionalised phosphine ligand

By Martyn Coles and Peter Hitchcock

Abstract

Structural investigation of Li-complexes of the phospha(III)-guanidinate anion [Ph2PC{(NPr)-Pr-i}(2)](-) revealed variable coordination to lithium; synthesis of the dimethyl aluminium compound, (Ph2PC{(NPr)-Pr-i}(2))AlMe2, which behaves as a metal-functionalised phosphine ligand towards platinum, is reported

Publisher: RSC Publishing
Year: 2002
OAI identifier: oai:sro.sussex.ac.uk:31223
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