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Unusual reactivity of a nickel N-heterocyclic carbene complex: tert-butyl group cleavage and silicone grease activation

By Stephen Caddick, F Geoffrey N Cloke, Peter B Hitchcock and Alexandra K de K Lewis

Abstract

Reaction lubrication? The reaction between [Ni(1,5-cod)2] (cod=cyclooctadiene) and 1,3-bis-tert-butylimidazol-2-ylidene in the presence of silicone grease affords the siloxane bridged dimer [{Ni[C(NtBuCH) 2][O(Me2SiOSiMe2)-µ-O]}2]. In a greaseless apparatus, the same reaction yields the dimer 1 (see structure), via two structurally characterized intermediates

Year: 2004
OAI identifier: oai:sro.sussex.ac.uk:28975
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