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Crystal structures of potassium trifluorido(4-methoxyphenyl)borate and potassium trifluorido(4-fluorophenyl)borate

By William T. A. Harrison and James L. Wardell


The title compounds, K+·C7H7BF3O−, (I), and K+·C6H4BF4−, (II), are molecular salts containing para-substituted phenyltrifluoridoborate anions. In each compound, the B atom adopts a distorted tetrahedral BCF3 geometry. Despite their different compositions and space groups, the irregular KF8 coordination polyhedra of the potassium cations in the structures are almost identical. These polyhedra share faces and edges, generating infinite (010) layers in (I) and infinite (001) layers in (II). In (I), adjacent layers are stacked in an AAA… fashion, whereas in (II), they are stacked in an ABAB… sequence

Topics: crystal structure, boron, Lewis acid, layered structure, Chemistry, QD1-999
Publisher: International Union of Crystallography
Year: 2014
DOI identifier: 10.1107/S1600536814009684
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